Chlorophenol — persistent organic pollutant

Pentachlorophenol in the bedroom

Pentachlorophenol is a chlorophenol that was widely used to protect wood from fungal decay and to prevent mold on textiles during storage and shipping. IARC classifies it as a Group 1 carcinogen, and it was added to the Stockholm Convention in 2015. It enters the bedroom through treated wooden bed frames and as a residue on imported textiles — a compound where the furniture and the fabric are the exposure pathways, not the mattress foam.

Pentachlorophenol — Embr Bedroom Chemistry Atlas

At a glance

Chemical familyChlorophenol (wood preservative / biocide)
CAS number87-86-5
ClassificationIARC Group 1 (carcinogenic to humans); Stockholm Convention POP (Annex A, 2015 listing)
Where you encounter itWood preservative for timber/bed frames; textile anti-mold treatment; imported textiles stored with PCP-treated materials
Sleep micro-environment relevanceTreated wooden bed frames, cotton/textile storage, and imported bedding products

Regulatory & certification status

Where pentachlorophenol stands across the major regulatory systems. Each row links to the governing instrument; where a jurisdiction has no specific measure, that is stated plainly rather than left blank.

Stockholm ConventionListed under Annex A (elimination) in 2015. Regulatory
EU REACHBanned; concentration limit >5 mg/kg (5 ppm) in substances and mixtures. Regulatory
US EPAMost registrations cancelled (2022 final cancellation order); limited utility-pole exemption. Regulatory
California Prop 65Listed as a carcinogen. Regulatory
OEKO-TEX STD 100Restricted — 0.05 ppm (baby) / 0.5 ppm (other product classes). Industry

What it is

Pentachlorophenol is a chlorophenol that was widely used as a wood preservative (protecting against fungal decay and termites) and as an anti-mold agent on textiles during storage and shipping. IARC classifies it as a Group 1 carcinogen. Peer-reviewed — IARC Monographs Vol. 117 It was added to the Stockholm Convention in 2015 as a persistent organic pollutant targeted for elimination. Regulatory — Stockholm Convention

How it relates to the bedroom

Treated wooden bed frames

PCP appears in the bedroom primarily through treated wooden bed frames and furniture. Older pressure-treated wood can continue to off-gas PCP for years. Most modern bed frames use untreated wood or alternative preservatives, but older frames and some imported products may still contain PCP-treated components. Indoor air and dust in homes with PCP-treated wood show measurable levels. Inferred — from wood-treatment persistence data and indoor air studies

Textile storage and shipping

PCP was also applied to cotton and textile bales during storage and shipping to prevent mold, meaning imported bedding products may carry residues. This pathway is less common in regulated markets today, but it persists in global supply chains — particularly for unbranded or low-cost textiles that bypass certification screening.

The US EPA cancellation

In 2022, the US EPA issued a final cancellation order for remaining PCP wood-preservative registrations, with a narrow exemption for existing utility-pole treatments. Regulatory — US EPA 2022 This means new PCP-treated wood products are no longer entering the market, but existing treated wood — including bed frames and structural timber installed decades ago — remains in use.

What the research says

  • Group 1 carcinogen. IARC classified PCP and some related compounds as carcinogenic to humans in 2019, based on sufficient evidence linking PCP exposure to non-Hodgkin lymphoma. Peer-reviewed — IARC Monographs Vol. 117
  • Stockholm Convention POP. Listed under Annex A in 2015 for global elimination. Regulatory
  • Textile screening. OEKO-TEX Standard 100 restricts PCP at 0.05 ppm for baby textiles and 0.5 ppm for other product classes — among the strictest limits for any chlorophenol. Industry — OEKO-TEX

What helps reduce it

Check the age and treatment of wooden bed frames. If your bed frame predates the 1990s and is made of pressure-treated wood, it may contain PCP. Sealing or replacing old treated-wood components is the most direct control.

Buy certified textiles. OEKO-TEX Standard 100 screens for PCP at strict limits. For imported bedding, choosing certified products is the most practical way to avoid residues from textile-storage treatments.

Ventilate. PCP can volatilize slowly from treated wood. Fresh-air exchange reduces indoor air concentrations.

Dust removal. PCP from treated wood settles into household dust. Regular HEPA vacuuming and wet-wiping reduce the dust reservoir.

What does NOT help

  • Assuming "new" means "safe." PCP is no longer applied to new products in most regulated markets, but it persists in existing treated wood and in global textile supply chains that do not follow the same standards.
  • Surface cleaning treated wood. PCP is pressure-impregnated deep into the wood, not just on the surface. Wiping a treated bed frame does not remove the source — it only captures what has already migrated to the surface.

Open research questions

  • The rate of PCP off-gassing from aged pressure-treated wood in typical bedroom conditions (temperature, humidity, ventilation). Speculation
  • The prevalence of PCP residues on imported textiles in markets without OEKO-TEX or equivalent screening. Speculation

Citations

  1. IARC (2019). Pentachlorophenol and some related compounds — Group 1 carcinogen. IARC Monographs Vol. 117. Peer-reviewed
  2. Stockholm Convention on Persistent Organic Pollutants — Pentachlorophenol listing, Annex A (2015). Regulatory
  3. US EPA (2022). Pentachlorophenol — Final cancellation order for remaining wood-preservative uses. Regulatory

Frequently asked questions

  • Can my wooden bed frame release pentachlorophenol?

    If the wood was pressure-treated with PCP — common for outdoor and structural timber through the 1980s — it can release PCP vapour for years. Most modern bed frames use untreated wood or alternative preservatives, but older frames and some imported products may still contain PCP-treated components.

  • Is pentachlorophenol still found in textiles?

    PCP is largely phased out of textile treatment in regulated markets, but it can appear as a residue on imported goods — particularly cotton and natural fibres stored or shipped using PCP as a mold inhibitor. OEKO-TEX Standard 100 screens for it at strict limits (0.05 ppm for baby textiles). Buying certified products is the most practical control.

Related compounds


Embr is a sleep environment company researching and addressing the chemistry of the bedroom. Research and product development in progress.

Last reviewed 2026-07-07. If you find a factual error, contact us.